Figure - available from: Topics in Current Chemistry
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Complicated strategies for coordination environment modulating and performance regulation of SACs. a Electrocatalytic performance promoting of single-atomic Fe sites by adjacent Te atoms for CO2RR. b Free-energy diagram of CO2RR to CO over Ni2-N4-C2, Ni-N3-C and Ni4-N-C models. c Regulating the FeN4 moiety by constructing Fe–Mo dual-metal atom sites for efficient electrochemical ORR. d S-anion-coordinated Ru-N-C catalyst for ORR. e Schematic of SACs, highlighting first and second coordination spheres and center active metal
Source publication
Metal-based catalysts, encompassing both homogeneous and heterogeneous types, play a vital role in the modern chemical industry. Heterogeneous metal-based catalysts usually possess more varied catalytically active centers than homogeneous catalysts, making it challenging to regulate their catalytic performance. In contrast, homogeneous catalysts ha...
Citations
The support is pivotal for stabilizing single metal atom and contributes to enhance the catalytic activity of single-atom catalysts (SACs). With the merits of versatile structures, tailored electronic structure, as...
