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Chronoamperometric curves and EIS spectra of (a) PEO/LiTFSI, (b) PEO–5%HUT4Li, (c) PEO–10%HUT4Li, and (d) PEO–15%HUT4Li

Chronoamperometric curves and EIS spectra of (a) PEO/LiTFSI, (b) PEO–5%HUT4Li, (c) PEO–10%HUT4Li, and (d) PEO–15%HUT4Li

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The active Li⁺ was coordinated with the zwitterionic part (squaric acid) of HUT4 by mechanical grinding to prepare a metal covalent organic framework HUT4Li, which was used as the filler of PEO and PPC composite polymer electrolytes (CPEs). The Li⁺ on the surface of HUT4Li can bind to oxygen atoms in PEO and PPC substrates as Lewis acid sites to pr...