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Cold plasma coating technology for surface functionalization of pharmaceutical powder particles is a promising approach to introduce new characteristics such as controlled release layers, improved powder flow properties, stability coatings, and binding of active components to the surface. This is typically achieved in a fluidized bed reactor, where...
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The aim of this research is to examine the techno-economic viability of both off-grid and on-grid hybrid renewable energy systems for Jordan's Al-Karak governorate. Hybrid Optimization of Multiple Energy Resources (HOMER) Pro software was used in this article to evaluate the carry feasibility to maximize the renewable energy (RE) integration in hybrid energy systems based on different configurations, grid-connected and stand-alone systems of the wind turbine, biogas plant, photovoltaic (PV) panels, flywheel, and batteries while minimizing the net present cost, the Levelized cost of energy and CO2 emissions mitigation. The results showed that the PV/Wind system, connected to the grid with batteries for storage is the optimal configuration for sustainable Al-Karak governorate electrification whilst achieving environmental benefits and guaranteeing reliable and continuous energy access with the lowest net present cost and the Levelized cost, 298,359 USD$ and 0.024 USD$/kWh respectively, and high RE share, 71.8% of electricity is generated from wind and 28.2% is purchased from the grid and emits 220 tons of CO2 per year, 53% less than a grid alone system. Such a system would provide advantages in terms of energy independence and improved environmental quality.
Ultrasounds are already broadly exploited in clinical diagnostics and are now becoming a powerful and not harmful tool in antitumoral therapies, as they are able to produce damages towards cancer cells, thank to inertial cavitation and temperature increase. The use of US alone or combined to molecular compounds, microbubbles or solid-state nanoparticles is the focus of current research and clinical trials, like thermoablation, drug sonoporation or sonodynamic therapies. In the present work, we discuss on the non-thermal effects of ultrasound and the conditions which enable oxygen radical production and which role they can have in provoking the death of different cancer cell lines. In this perspective, we set a mathematical model to predict the pressure spatial distribution in a defined water sample volume and thus obtain a map of acoustic pressures and acoustic intensities of the applied ultrasound at different input powers. We then validate and verify these numerical results with direct acoustic measurements and by detecting the production of reactive oxygen species (ROS) by means of sonochemiluminescence (SCL) and electron paramagnetic resonance (EPR) spectroscopy, applied to the same water sample volume and using the same US input parameters adopted in the simulation. Finally, the various US conditions are applied to two different set of cancer cell lines, a cervical adenocarcinoma and a hematological cancer, Burkitt’s lymphoma. We hypothesize how the ROS generation can influence the recorded cell death. In a second set of experiments, the role of semiconductor metal oxide nanocrystals, i.e. zinc oxide, is also evaluated by adding them to the water and biological systems. In particular, the role of ZnO in enhancing the ROS production is verified. Furthermore, the interplay among US and ZnO nanocrystals is evaluated in provoking cancer cell death at specific conditions. This study demonstrates a useful correlation between numerical simulation and experimental acoustic validation as well as with ROS measurement at both qualitative and quantitative levels during US irradiation of simple water solution. It further tries to translate the obtained results to justify one of the possible mechanisms responsible of cancer cell death. It thus aims to pave the way for the use of US in cancer therapy and a better understanding on the non-thermal effect that a specific set of US parameters can have on cancer cells cultured in vitro.
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The complex nature of the physics of solid-gas interactions in concentrated solar particle heat exchangers signifies the need to develop new and cutting-edge numerical models to understand these interactions with the overarching goal of optimizing industrial solar thermal processes. To this end, a coupled computational fluid dynamics and discrete element method is developed to unravel near-wall particle flow physics of solar industrial heat exchangers. In addition, advanced post-processing functions are developed to provide a high-end data visualization and quantitative assessment of the packing distribution of solar particle heat exchangers. The validated numerical model shows that the particle temperature varies considerably throughout the entire fluid filled packed particle bed and it is shown that thermal radiation contribution becomes more profound at higher operating temperatures, namely 1073–1173 K. Also, the temperatures and solid volume fractions of the near-wall particles differ greatly compared to the bulk particles. The methods presented herein can be implemented by engineers and scientists to evaluate near-wall packing distributions and thermal characteristics, which would be useful for optimizing the geometric morphology of solar industrial heat exchangers.
In this study, numerical simulations of the behaviour of large-size sandstone specimens exposed to wood crib fires were conducted. The developed numerical model, which innovatively considers the reversible quartz expansion behaviour during heating–cooling cycles, can replicate the temperature distributions, cracking behaviours, and strength variations of sandstone samples under various thermal loads (e.g., fires). Results show that the cracking mechanisms during heating and cooling are different, and the spalling is due to their combining effects. During the heating process, tensile stresses are induced mainly inside the sample due to significant expansions of the outer layer. The induced tensile microcracks beneath the surface will be furtherly extended and widened due to the re-distributed local stresses caused by local failures. After the fire, significant tensile stresses appear in the outer part of the sample due to the increased thermal gradients (i.e., volumetric expansions) of the inner part, leading to crack widening on the surface. These widened cracks will coalesce with the heating-induced cracks in the earlier time and boost the fracturing and spalling behaviour until the temperature across the sample reaches an equilibrium state. The findings are essential for understanding the failure mechanism of sandstone during real fire development. The good agreements between lab tests and numerical simulation also reveal the feasibility of using numerical models to predict the fire-induced damage in sandstone elements in architecture.
