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5: 1 H-NMR spectrum of 14 and 1 equiv. of benzaldehyde in MeOD-d 4 before (in blue) and after (in red) addition of H 2 (80 bar).

5: 1 H-NMR spectrum of 14 and 1 equiv. of benzaldehyde in MeOD-d 4 before (in blue) and after (in red) addition of H 2 (80 bar).

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Inspired by Nature several groups have developed structural and functional iron complexes mimicking the active site of the iron-hydrogenases, which show high reactivity in the H2 cleavage. Usually pendant bases have been incorporated onto families of Fe complexes in order to achieve active systems. In the view of these recent developments, in chapt...